Maintenance Notice (10:00 PM July 18 - 1:00 AM July 21, 2025 UTC): This website is scheduled to be unavailable due to maintenance. Maintenance may be completed earlier than scheduled. We appreciate your patience and understanding.
Product Document Searching Made Easy by 2D Code! | TCI Materials Science News July 2025 | [Product Highlights] Travoprost with Intra-Ocular-... | Various analytical charts can be searched on each product detail page and Product Document Search (The kinds of analytical charts differ by product)
Maximum quantity allowed is 999
Please select the quantity
p-Methoxyphenylglycosides
A thoughtful choice of anomeric blocking group is often of conclusive importance for the success of an oligosaccharide synthesis. The anomeric blocking group is required stability towards the reaction conditions employed and easy transformation into an activated derivative for further glycosylation.
The p-methoxyphenyl group is useful anomeric blocking group which is removed selectively by treatment with ceric ammonium nitrate, to give the corresponding glycosyl halides and thiophenyl glycosides in high yields. Furthermore, they are stable under most of the conditions used in oligosaccharide synthesis.
The p-methoxyphenyl group is useful anomeric blocking group which is removed selectively by treatment with ceric ammonium nitrate, to give the corresponding glycosyl halides and thiophenyl glycosides in high yields. Furthermore, they are stable under most of the conditions used in oligosaccharide synthesis.
References
- 1) T. Nakano, Y. Ito, T. Ogawa, Tetrahedron Lett. 1990, 31, 1597.
- 2) M. Mori, Y. Ito, T. Ogawa, Carbohydr. Res. 1989, 192, 131.
- 3) Y. Matsuzaki, Y. Ito, T. Ogawa, Tetrahedron Lett. 1992, 33, 4025.
- 4) A. Dan, Y. Ito, T. Ogawa, J. Org. Chem. 1995, 60, 4680.
- 5) C. Murakata, T. Ogawa, Carbohydr. Res. 1992, 235, 95.
- 6) H. Kuyama, T. Nukada, Y. Nakahara, T. Ogawa, Tetrahedron Lett. 1993, 34, 2171.
- 7) Z. Zhang, G. Mugnusson, Carbohydr. Res. 1996, 925, 41.