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CAS RN: 42152-46-5 | Product Number: T1442
Copper(I) Trifluoromethanesulfonate Benzene Complex
Purity: >90.0%(T)
Synonyms:
- Copper(I) Triflate Benzene Complex
- Trifluoromethanesulfonic Acid Copper(I) Salt Benzene Complex
Product Documents:
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| Product Number | T1442 |
Purity / Analysis Method
|
>90.0%(T) |
| Molecular Formula / Molecular Weight | CCuF__3O__3S·^^1/__2C__6H__6 = 251.67 |
| Physical State (20 deg.C) | Solid |
Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 42152-46-5 |
| Reaxys Registry Number | 14355676 |
| PubChem Substance ID | 87577205 |
| MDL Number | MFCD00043300 |
Specifications
| Appearance | White to Light yellow to Light orange powder to crystal |
| Purity(Potassium permanganate method) | min. 90.0 % |
Properties (reference)
| Melting Point | 160 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H228 : Flammable solid. |
| Precautionary Statements | P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| UN Number | UN3175 |
| Class | 4.1 |
| Packing Group | II |
| H.S.code* | 2904.10-000 |
Application
Photocycloaddition

References
- R. G. Salomon, J. K. Kochi, Tetrahedron Lett. 1973, 14, 2529.

- R. G. Salomon, K. Folting, W. E. Streib, J. K. Kochi, J. Am. Chem. Soc. 1974, 96, 1145.

- R. G. Salomon, D. J. Coughlin, E. M. Easler, J. Am. Chem. Soc. 1979, 101, 3961.

- R. G. Salomon, S. Ghosh, Org. Synth. Coll. Vol. 7, 177.
- R. G. Salomon, J. K. Kochi, J. Chem. Soc., Chem. Commun. 1972, 559.

- R. G. Salomon, J. K. Kochi, J. Am. Chem. Soc. 1973, 95, 3300.

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