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CAS RN: 924-44-7 | Product Number: G0264
Ethyl Glyoxylate Polymer form (47% in Toluene)
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Purity:
Synonyms:
- Ethyl Oxoacetate Polymer form (47% in Toluene)
- Glyoxalic Acid Ethyl Ester Polymer form (47% in Toluene)
- Glyoxylic Acid Ethyl Ester Polymer form (47% in Toluene)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 25G |
41,00 €
|
14 | ≥80 |
|
|
| 100G |
110,00 €
|
1 | ≥40 |
|
|
| 500G |
431,00 €
|
Contact Us | Contact Us |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
This product cannot be shipped to Russia and Turkey.
| Product Number | G0264 |
| Molecular Formula / Molecular Weight | (CH__3CH__2OCOCHO)__n |
| Physical State (20 deg.C) | Liquid |
Storage Temperature 
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 924-44-7 |
| Reaxys Registry Number | 1209486 |
| PubChem Substance ID | 87570438 |
| MDL Number | MFCD00044009 |
Specifications
| Appearance | Colorless to Almost colorlessclear liquid |
| Concentration(Oxime Formation) | 47.0 to 51.7 w/w% |
Properties (reference)
| Boiling Point | 110 °C |
| Flash point | 7 °C |
| Specific Gravity (20/20) | 1.03 |
| Refractive Index | 1.48 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H332 : Harmful if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H335 : May cause respiratory irritation. H361d : Suspected of damaging the unborn child. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P331 : Do NOT induce vomiting. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 213-105-3 |
Transport Information:
| UN Number | UN1294 |
| Class | 3 |
| Packing Group | II |
| HS Number | 2918300090 |
Application
Preparation of Monomeric Ethyl Glyoxylate
Polymeric ethyl glyoxylate toluene solution (30 g) was added to the flame dried flask. Toluene was evaporated completely under vacuum (less than 1 mmHg) at room temperature, and phosphorus pentoxide (ca. 300 mg) was added to the polymeric ethyl glyoxylate. The mixture was distilled to give almost-toluene-free monomeric ethyl glyoxylate as a slightly yellow liquid (150 mmHg, 80 °C). Monomeric ethyl glyoxylate easily polymerizes within 30 min to give viscous liquid. Therefore, distilled ethyl glyoxylate should be used immediately after purification.
References
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