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Published TCIMAIL newest issue No.201
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CAS RN: 56252-55-2 | Product Number: M1211
Methylaluminum Bis(2,6-di-tert-butyl-4-methylphenoxide) (0.4mol/L in Toluene)
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Purity:
Synonyms:
- Bis(2,6-di-tert-butyl-4-methylphenoxy)methylaluminum (0.4mol/L in Toluene)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 50ML |
98,00 €
|
8 | Ships within 1 month after ordering |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
This product cannot be shipped to Russia and Turkey.
| Product Number | M1211 |
| Molecular Formula / Molecular Weight | C__3__1H__4__9AlO__2 = 480.71 |
| Physical State (20 deg.C) | Liquid |
Storage Temperature 
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive,Heat Sensitive |
| Packaging and Container
|
50ML-DualSeal Bottle (View image) |
| CAS RN | 56252-55-2 |
| Reaxys Registry Number | 4039280 |
| PubChem Substance ID | 87573171 |
| MDL Number | MFCD00079652 |
Specifications
| Appearance | Colorless to Light orange to Yellow clear liquid |
| Concentration(Chelometric Method) | 19.0 to 24.0 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Specific Gravity (20/20) | 0.89 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H332 : Harmful if inhaled. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H335 : May cause respiratory irritation. H361d : Suspected of damaging the unborn child. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H225 : Highly flammable liquid and vapour. H261 : In contact with water releases flammable gases. |
| Precautionary Statements | P231 + P232 : Handle and store contents under inert gas. Protect from moisture. P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN3399 |
| Class | 4.3 / 3 |
| Packing Group | II |
| HS Number | 2942000090 |
Application
Amphiphilic Reaction
References
- Amphiphilic reactions
- Conjugate reduction of α, β-unsaturated ketones
- Other applications
- a) Molecular recognition of ethers
- b) MAD reverses the diastereoselectivity of the addition of methylmetallics to a β-keto ether
- c) Altering the stereochemistry of allylation reactions of cyclic α-sulfinyl radicals
- d) High-speed polymerization of methyl methacrylate
- Review
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
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