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CAS RN: 26456-05-3 | Product Number: M1787
10-Methylacridinium Perchlorate
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Purity: >98.0%(N)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 250MG |
€ 51,00
|
Ships within 3 weeks after ordering | 11 |
|
|
| 1G |
€ 166,00
|
Contact Us | 9 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | M1787 |
Purity / Analysis Method 
|
>98.0%(N) |
| Molecular Formula / Molecular Weight | C__1__4H__1__2ClNO__4 = 293.70 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 26456-05-3 |
| Reaxys Registry Number | 3647072 |
| PubChem Substance ID | 87559032 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(with Total Nitrogen) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 241 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P220 : Keep away from clothing and other combustible materials. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. |
Related Laws:
Transport Information:
| UN Number | UN1479 |
| Class | 5.1 |
| Packing Group | III |
| HS Number | 2933998090 |
Application
Baeyer–Villiger Oxidation with 10-Methylacridinium as an Organocatalyst
Typical Procedure:
Cyclobutanone (0.5 mmol) and 10-methylacridinium perchlorate (7.4 mg, 0.025 mmol) are dissolved in CH3CN (1 mL). Hydrogen peroxide (68 µL, 30% solution in water, 0.6 mmol) is added and the mixture is irradiated with a 450 W high-pressure mercury lamp in a Pyrex® flask (λ>320 nm) at room temperature for 20 h. The course of the reaction is monitored by TLC. After completion of the reaction, solvent is evaporated in vacuum. Purification of the residue by column chromatography (silica gel, ethyl acetate/petroleum ether gradient) yields the corresponding lactone.
Cyclobutanone (0.5 mmol) and 10-methylacridinium perchlorate (7.4 mg, 0.025 mmol) are dissolved in CH3CN (1 mL). Hydrogen peroxide (68 µL, 30% solution in water, 0.6 mmol) is added and the mixture is irradiated with a 450 W high-pressure mercury lamp in a Pyrex® flask (λ>320 nm) at room temperature for 20 h. The course of the reaction is monitored by TLC. After completion of the reaction, solvent is evaporated in vacuum. Purification of the residue by column chromatography (silica gel, ethyl acetate/petroleum ether gradient) yields the corresponding lactone.
References
PubMed Literature
Product Articles
[Research Articles] Baeyer–Villiger Oxidation with 10-Methylacridinium as an Organocatalyst
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