Maintenance Notice (12:30 AM - 4:00 AM June 8, 2025): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Published TCIMAIL newest issue No.198
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 100-63-0 | Product Number: P0183
Phenylhydrazine
×
![]()
×
Purity: >98.0%(GC)(T)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 25G |
€16.00
|
12 | ≥100 |
|
| 100G |
€23.00
|
19 | ≥40 |
|
| 500G |
€87.00
|
2 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | P0183 |
| Purity / Analysis Method | >98.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__6H__8N__2 = 108.14 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive |
| CAS RN | 100-63-0 |
| Reaxys Registry Number | 606080 |
| PubChem Substance ID | 87574432 |
| SDBS (AIST Spectral DB) | 561 |
| Merck Index (14) | 7293 |
| MDL Number | MFCD00007573 |
Specifications
| Appearance | White or Colorless to Orange to Green powder to lump to clear liquid |
| Purity(GC) | min. 98.0 % |
| Purity( Potassium iodate Method) | min. 98.0 % |
Properties (reference)
| Melting Point | 19 °C |
| Flash point | 88 °C |
| Specific Gravity (20/20) | 1.10 |
| Refractive Index | 1.61 |
| Degree of solubility in water | 145 g/l 25 °C |
| Solubility (miscible with) | Ether, Alcohol, Benzene, Chloroform |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H310 : Fatal in contact with skin. H301 + H331 : Toxic if swallowed or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H341 : Suspected of causing genetic defects. H350 : May cause cancer. H400 : Very toxic to aquatic life. |
| Precautionary Statements | P273 : Avoid release to the environment. P262 : Do not get in eyes, on skin, or on clothing. P260 : Do not breathe mist or vapours. P201 : Obtain special instructions before use. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P391 : Collect spillage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P352 + P310 : IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. |
Related Laws:
| EC Number | 202-873-5 |
| RTECS# | MV8925000 |
Transport Information:
| UN Number | UN2572 |
| Class | 6.1 |
| Packing Group | II |
| HS Number | 2928009090 |
Application
Reagent for anemia model
References
- Screening of toxic-haemolytic anaemia in laboratory rats: a model of phenylhydrazine-induced haemolysis
- J. Berger, Haematologia (Budap) 1985, 18, 193.
- The effect of macrocytosis on rat erythrocyte deformability during recovery from phenylhydrazine-induced anemia
- J. M. Norton, Biorheology 1990, 27, 21.
- Effect of Tectona grandis on phenylhydrazine-induced anaemia in rats
- Cardiac remodelling, blood chemistry, haematology and oxygen consumption of Atlantic cod, Gadus morhua L., induced by experimental haemolytic anaemia with phenylhydrazine
Application
Direct Radical Arylation of Unactivated Arenes Using Phenyl Hydrazine
Typical Procedure: KOt-Bu (0.101 g, 0.9 mmol, 3.0 eq.), aryl iodide (0.3 mmol, 1.0 eq.) and benzene (2.8 mL) are added into a flame dried Schlenk tube under argon atmosphere. Then a 0.15 M solution of phenylhydrazine (0.2 mL, 0.03 mmol, 0.1 eq.) in benzene is added to this heterogeneous reaction mixture over 6 h using a syringe pump at 100 °C. After complete addition, the reaction mixture is stirred for an additional 24 h at 100 °C. After that it is cooled to room temperature, quenched with water (4 mL) and subsequently extracted with ethyl acetate (3 x 20 mL). The combined organic phase is washed with brine (5 mL), dried over anhydrous Na2SO4, filtered and concentrated under vacuum. The crude product is purified by flash column chromatography using pentane or a 95:05 mixture of pentane/ethyl acetate as an eluent.
References
PubMed Literature
Product Articles
[Research Articles] Direct Radical Arylation of Unactivated Arenes Using Phenyl HydrazineProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.