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CAS RN: 2043361-32-4 | Product Number: B5480

AlkylFluor™


Purity: >97.0%(N)
Synonyms:
  • 1,3-Bis(2,6-diisopropylphenyl)-2-fluoroimidazolium Tetrafluoroborate
Documents:
200MG
€88.00
Contact Us ≥20 
1G
€266.00
2   ≥20 

*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).


Note:

Sold under PCT/US12/33125, licensed from President and Fellows of Harvard College.

Product Number B5480
Purity / Analysis Method >97.0%(N)
Molecular Formula / Molecular Weight C__2__7H__3__6BF__5N__2 = 494.4  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 2043361-32-4
PubChem Substance ID 354334448
Specifications
Appearance White to Orange to Green powder to crystal
Purity(with Total Nitrogen) min. 97.0 %
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
Precautionary Statements P260 : Do not breathe dust or mist.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
Transport Information:
UN Number UN1759
Class 8
Packing Group II
HS Number 2933299090
Application
AlkylFluorTM: Stable Reagent for Deoxyfluorination of Primary and Secondary Alcohols

Experimental procedure: An oven-dried vial is charged with potassium fluoride (58.1 mg, 1.00 mmol, 5.00 eq.) and AlkylFluor (118.7 mg, 0.240 mmol, 1.20 eq.), and heated at 100 °C for 1 h under vacuum (~0.1 mbar). The mixture is cooled to room temperature, then alcohol (0.200 mmol, 1.00 eq.) is added quickly. The vial is sealed, then evacuated and backfilled with nitrogen. Dioxane (3 mL) is added and the reaction mixture is heated at the appropriate temperature with vigorous stirring. Upon completion, the reaction mixture is cooled to room temperature and filtered through a pad of Celite, eluting with dichloromethane (3 × 1 mL). The filtrate is concentrated in vacuo and the residue is purified by flash column chromatography to afford the desired alkyl fluoride.

References


PubMed Literature


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