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CAS RN: 1420042-07-4 | Product Number: D5160

2,4-Dibromo-6-[(E)-[[(1R,2R)-2-(isoindolin-2-yl)-1,2-diphenylethyl]imino]methyl]phenol


Purity: >93.0%(HPLC)
Synonyms:
Documents:
50MG
€202.00
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Product Number D5160
Purity / Analysis Method >93.0%(HPLC)
Molecular Formula / Molecular Weight C__2__9H__2__4Br__2N__2O = 576.33  
Physical State (20 deg.C) Solid
Storage Temperature <0°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive,Heat Sensitive
CAS RN 1420042-07-4
Reaxys Registry Number 28661479
PubChem Substance ID 354334487
Specifications
Appearance Light yellow to Yellow to Orange powder to crystal
Purity(HPLC) min. 93.0 area%
Properties (reference)
GHS
Related Laws:
Transport Information:
HS Number 2933998090
Application
Chiral Ligand for Asymmetric Iodocyclization

Experimental procedure: N-Ts alkenamide (0.1 mmol) and D5160-CuOAc complex (7.0 mg, 0.01 mmol) are dissolved in dichloromethane (1 mL) and toluene (3 mL). The mixture is stirred at room temperature for 10 min, and at -78 °C for 30 min. Then, NIS (24.6 mg, 0.11 mmol) and I2 (5.1 mg, 0.02 mmol) are added to the reaction mixture. After being stirred for 16-18 h, the reaction mixture is quenched with saturated Na2SO3 aq. and then the products are extracted with dichloromethane in 3 times. The collected organic layer is dried over Na2SO4. After removal of the solvent under reduced pressure, the residue is purified by silica-gel column chromatography (hexane:ethyl acetate = 3:1) to afford the iodocyclization product.

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