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CAS RN: 496-15-1 | Product Number: I0033

Indoline


Purity: >98.0%(GC)(T)
Synonyms:
  • 2,3-Dihydroindole
Documents:
25ML
€18.00
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250ML
€128.00
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Product Number I0033
Purity / Analysis Method >98.0%(GC)(T)
Molecular Formula / Molecular Weight C__8H__9N = 119.17  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
CAS RN 496-15-1
Reaxys Registry Number 111915
PubChem Substance ID 87571442
SDBS (AIST Spectral DB) 1358
MDL Number

MFCD00005705

Specifications
Appearance Colorless to Orange to Green clear liquid
Purity(GC) min. 98.0 %
Purity(Nonaqueous Titration) min. 98.0 %
Properties (reference)
Boiling Point 231 °C
Flash point 93 °C
Specific Gravity (20/20) 1.07
Refractive Index 1.59
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
EC Number 207-816-8
RTECS# NL6906300
Transport Information:
HS Number 2933998090
Application
Catalytic Formylation Using Indoline

I0033

Experimental procedure:
Alkenylboronic acids (0.12 mmol, 1.2 eq.) and glyoxylic acid monohydrate (0.1 mmol, 1.0 eq., 9.2 mg) are placed in a flask. Acetonitrile (1.0 mL) is injected into the vial and then indoline (0.03 mmol, 3.4 µL) is added. The mixture is stirred at room temperature for 24 h exposed to air. After stirred for 24 h, the residue is purified by column chromatography (SiO2, hexanes:EtOAc) to provide the corresponding compounds.

References


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