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CAS RN: 3094-87-9 | Product Number: I0765

Iron(II) Acetate

Purity: >90.0%(T)
  • Acetic Acid Iron(II) Salt
1   ≥20 
1   ≥20 

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Product Number I0765
Purity / Analysis Method >90.0%(T)
Molecular Formula / Molecular Weight C__4H__6O__4Fe = 173.93  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 3094-87-9
Reaxys Registry Number 3996045
PubChem Substance ID 125307293
MDL Number


Appearance White to Gray to Brown powder to crystal
Purity(Potassium permanganate method) min. 90.0 %
Properties (reference)
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
EC Number 221-441-7
RTECS# AI3850000
Transport Information:
HS Number 2915290090
Iron-catalyzed direct arylation

Typical procedure: To a dried vessel under argon atmosphere, the Fe(OAc)2 (4.5 mg), bathophenanthroline (16.6 mg), crushed dry KOtBu (112 mg), iodobenzene (102 mg) and benzene (3.9 g) were added. The reaction was stirred at room temperature for 20 min and then at 80 °C for 20 h. After cooling a mixture of CH2Cl2 / hexane (1:1) (2 mL) was added, and the solution was filtered through a silica pad. The pad was then rinsed with CH2Cl2 / hexane (1:1) (15 mL). The combined solutions were concentrated and the crude mixture was purified by column chromatography (eluent: hexanes) to give biphenyl as a white solid (75 mg, 89 %).


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