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CAS RN: 903592-98-3 | 产品编码: B3235
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride
![Thumbnail of [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride](/medias/B3235.jpg?context=bWFzdGVyfHJvb3R8MTcxNTJ8aW1hZ2UvanBlZ3xhREptTDJoa05DODRPVE16TlRnNE56STVPRGcyTDBJek1qTTFMbXB3Wnd8MWVmYzZkNDZmOTI2NjIxOGQwNjQwNTA3YTU4MjE3OGMzMWE1MWEzNTgxMDUxZTNjY2I3ZTNmNjBmOTE2Zjg1NQ "[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride")
![Chemical Structure of [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride](/medias/B3235.jpg?context=bWFzdGVyfHJvb3R8NjAwMjd8aW1hZ2UvanBlZ3xhRGMzTDJnM09DODRPVEl3TVRBNU5ERTJORGM0TDBJek1qTTFMbXB3Wnd8MmViZjhhOTY5Y2ViZjEwYTk3Mzg3MWE0NDQxNTk3YmMwMWUxNDQ0ZWIxOGNhNTRjMzdlYWZjZDg2MDQzZDcwNg "[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride")
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补充产品信息:
NiCl2(PPh3)IPr
| 产品编码 | B3235 |
纯度/分析方法 
|
>98.0%(T) |
| 分子式/分子量 | C__4__5H__5__1Cl__2N__2NiP = 780.48 |
| 外观与形状（20°C） | 固体 |
| 储存温度
|
室温 (15°C以下阴凉干燥处) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 空气,湿气 (分解) |
| 包装和容器
|
1G-Glass Bottle with Plastic Insert （查看图片）, 200MG-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 903592-98-3 |
| PubChem物质ID | 87561164 |
技术规格
| Appearance | Yellow to Amber to Dark red powder to crystal |
| Purity(Chelometric Titration) | min. 98.0 % |
| NMR | confirm to structure |
物性（参考值）
GHS
| 象形图 |
|
| 信号词 | Danger |
| 危险性说明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P342 + P311 : If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P405 : Store locked up. |
相关法规
运输信息
| HS编码* | 2933.29-000 |
应用
Cross-Coupling Reaction of Grignard Regents with Aryl Thioethers
References
- Nickel–NHC-Catalyzed Cross-Coupling of 2-Methylsulfanylbenzofurans with Alkyl Grignard Reagents
- Ni-Catalyzed cross-coupling of aryl thioethers with alkyl Grignard reagents via C–S bond cleavage
应用
Kumada-Tamao-Corriu Cross-Coupling Reaction
References
- Synthesis and Structures of Nickel Halide Complexes Bearing Mono- and Bis-coordinated N-Heterocyclic Carbene Ligands, Catalyzing Grignard Cross-Coupling Reactions
应用
Controlled Polymerization Catalyst for Polythiophene
References
- C–H Functionalization Polycondensation of Chlorothiophenes in the Presence of Nickel Catalyst with Stoichiometric or Catalytically Generated Magnesium Amide
技术文章
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