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CAS RN: 894102-11-5 | 产品编码: B3354
Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide
![Chemical Structure of Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide](/medias/B3354.jpg?context=bWFzdGVyfHJvb3R8NTUxNzR8aW1hZ2UvanBlZ3xhRGMwTDJnMU55ODRPVEl3TVRFME9USXhOVEF5TDBJek16VTBMbXB3Wnd8OWNlYjllMzY3NDI0ODRkN2YyNzQ2Mzg0NjBmNDUyMTFiZTVhNjU1OTA5YjlkODMxNjU4YzQ1ZTFhNTc5NWUyNQ "Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide")
![Thumbnail of Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide](/medias/B3354.jpg?context=bWFzdGVyfHJvb3R8MTc1MTN8aW1hZ2UvanBlZ3xhRFkzTDJnME15ODRPVE16TlRrME1qTTBPVEV3TDBJek16VTBMbXB3Wnd8MzUxZDE1MzliNGQ4NTdjM2I4MTQ2ODRjZjFkMjVjYjc3NjZhMWQ0NjU2ZWJkZDlhNzJkN2Q4ZWIwMDNiNjY1Yw)
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![Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide")
| 规格 | 单价 | 同一天 | 2-3个工作日 | 左侧以上货期 | 数量 |
货期信息
|
|---|---|---|---|---|---|---|
| 1G |
S$355.50
|
5 | 0 | 下单后约2周内可以发货 |
|
| 产品编码 | B3354 |
纯度/分析方法 
|
>98.0%(T)(N) |
| 分子式/分子量 | C__1__3H__1__3Br__2N__5Ni = 457.78 |
| 外观与形状（20°C） | 固体 |
| 储存温度
|
室温 (15°C以下阴凉干燥处) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 湿气 (分解) |
| 包装和容器
|
1G-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 894102-11-5 |
| PubChem物质ID | 87561048 |
技术规格
| Appearance | Orange to Amber to Dark red powder to crystal |
| Purity(with Total Nitrogen) | min. 98.0 % |
| Purity(Chelometric Titration) | min. 98.0 % |
| NMR | confirm to structure |
物性（参考值）
GHS
| 象形图 |
|
| 信号词 | Danger |
| 危险性说明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P405 : Store locked up. |
相关法规
运输信息
| HS编码* | 2933.39-000 |
应用
Kumada-Tamao-Corriu Cross-Coupling Reaction
References
- Catalytic Activities of a Bis(carbene)-Derived Nickel(II)-Pincer Complex in Kumada-Tamao-Corriu and Suzuki-Miyaura Coupling Reactions for the Synthesis of Biaryl Compounds
应用
Suzuki-Miyaura Cross-Coupling Reaction
References
- Synthesis and Catalytic Activity of a Pincer-Type Bis(imidazolin-2-ylidene) Nickel(II) Complex
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