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CAS RN: 35138-22-8 | 产品编码: B3961
Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
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| 产品编码 | B3961 |
| 分子式/分子量 | C__1__6H__2__4BF__4Rh = 406.08 |
| 外观与形状（20°C） | 固体 |
储存温度 
|
冷藏 (0-10°C) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 空气,湿气 (吸湿),加热 |
| 包装和容器
|
100MG-Glass Bottle with Plastic Insert （查看图片）, 1G-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 35138-22-8 |
| Reaxys-RN | 14342367 |
| PubChem物质ID | 172088994 |
| MDL编号 | MFCD00075045 |
技术规格
| Appearance | Orange to Amber to Dark red powder to crystal |
| Elemental analysis(Carbon) | 44.50 to 49.00 % |
物性（参考值）
| 熔点 | 184 °C(dec.) |
GHS
| 象形图 |
|
| 信号词 | Danger |
| 危险性说明 | H314 : Causes severe skin burns and eye damage. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
相关法规
运输信息
| UN编号 | UN1759 |
| 类别 | 8 |
| 包装类别 | III |
| HS编码* | 2843.90-000 |
应用
Enantioselective Synthesis of Bicyclo Compounds Catalyzed by Rhodium and Benzoic Acid
Reference
应用
C-H Activation Reaction for Aryl Ketones
Reference
- Cationic Rh(I)/Modified-BINAP-Catalyzed Reactions of Carbonyl Compounds with 1,6-Diynes Leading to Dienones and Ortho-Functionalized Aryl Ketones
应用
Enantioselective Isomerization of Allylic Alcohols
References
- Enantioselective Isomerization of Allylic Alcohols Catalyzed by a Rhodium/Phosphaferrocene Complex
- A Versatile New Catalyst for the Enantioselective Isomerization of Allylic Alcohols to Aldehydes: Scope and Mechanistic Studies
参考文献
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技术规格
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