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CAS RN: 852445-83-1 | 产品编码: C2405
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)
![Chemical Structure of Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)](/medias/C2405.jpg?context=bWFzdGVyfHJvb3R8NTQ5MTR8aW1hZ2UvanBlZ3xhRFJpTDJoaVlTODRPVEl3TnpRek5qQTRNelV3TDBNeU5EQTFMbXB3Wnd8ZWRmOTI4MGE0ODY4M2FiYTM5YmI0YTZkZDhmN2E2Y2QzNGZmN2I3ZjVjNzlkMGEzYWI3YjdjYjIzOTAxY2QyMQ "Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)")
![Thumbnail of Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)](/medias/C2405.jpg?context=bWFzdGVyfHJvb3R8MTY1NDN8aW1hZ2UvanBlZ3xhREJoTDJnM01DODRPVE0wTVRVNU9ERXdOVGt3TDBNeU5EQTFMbXB3Wnd8YjI5OTZlNjMxNWU4OTNhNjNhYWJjYzA3ZWQ4YzI2ZTk4MjYwNmRjNzAwMzZlOWI2MzE4NzVkZjY1ZjU3YWRjYQ)
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![Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)")
| 产品编码 | C2405 |
纯度/分析方法 
|
>98.0%(N) |
| 分子式/分子量 | C__2__7H__3__6AuClN__2 = 621.02 |
| 外观与形状（20°C） | 固体 |
| 储存温度
|
冷藏 (0-10°C) |
| 应避免的情况 | 加热 |
| 包装和容器
|
200MG-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 852445-83-1 |
| PubChem物质ID | 125307291 |
| MDL编号 | MFCD09839143 |
技术规格
| Appearance | White to Almost white powder to crystal |
| Purity(HPLC) | min. 94.0 area% |
| Purity(with Total Nitrogen) | min. 98.0 % |
| NMR | confirm to structure |
物性（参考值）
| 熔点 | 298 °C |
GHS
相关法规
运输信息
| HS编码* | 2843.30-000 |
应用
N-Heterocyclic Carbene (NHC) Gold Complex Catalyst
References
- AuI-catalyzed tandem [3,3] rearrangement-intramolecular hydroarylation: mild and efficient formation of substituted indenes
- Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes
- [(NHC)AuI]-catalyzed acid-free alkyne hydration at part-per-million catalyst loadings
应用
Regio- and stereoselective hydrofluorination reaction
Typical procedure: To a 2 mL polypropylene microcentrifuge tube is added the alkyne substrate (131 mg), PhN(CH3)3· HOTf (11 mg), Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) (6 mg), AgBF4 (2 mg) and CH2Cl2 (0.75 mL) are added. After stirring in the dark for 5 min, KHSO4 (40 mg) and Et3N· 3HF (100 micro-L) are added. The reaction is stirred in the dark for 15 h. The reaction mixture is transferred to a 15-mL polypropylene centrifuge tube. The reaction is quenched by adding excess Cs2CO3 to the reaction mixture until gas evolution ceased. The mixture is filtered through celite, which is subsequently rinsed with CH2Cl2 (5 mL). The solvent is removed in vacuo. The crude residue is purified by flash column chromatography to give the hydrofluorination product in 74% yield as a clear oil.
References
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