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CAS RN: 912823-79-1 | 产品编码: P1626
Pentafluoroanilinium Trifluoromethanesulfonate

产品编码 | P1626 |
纯度/分析方法 | >98.0%(T)(HPLC) |
分子式/分子量 | C__7H__3F__8NO__3S = 333.15 |
外观与形状(20°C) | 固体 |
储存温度 | 室温 (15°C以下阴凉干燥处) |
包装和容器 | 1G-Glass Bottle with Plastic Insert (查看图片) |
CAS RN | 912823-79-1 |
Reaxys-RN | 15026764 |
PubChem物质ID | 87558623 |
技术规格
Appearance | White to Light yellow to Dark green powder to crystal |
Purity(HPLC) | min. 98.0 area% |
Purity(Neutralization titration) | min. 98.0 % |
物性(参考值)
水溶性 | 可溶 |
GHS
象形图 |
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信号词 | Danger |
危险性说明 | H314 : Causes severe skin burns and eye damage. |
防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
相关法规
运输信息
UN编号 | UN1759 |
类别 | 8 |
包装类别 | III |
HS编码* | 2921.42-000 |
应用
Efficient Method for the Catalytic Esterification using Ammonium Triflate Catalyst
References
- Y. Tanabe, T. Misaki, H. Iida, Y. Arai, Yuki Gosei Kagaku Kyokaishi (J. Synth. Org. Chem., Jpn.) 2004, 62, 1249.
- T. Funatomi, K. Wakasugi, T. Misaki, Y. Tanabe, Green Chemistry, 2006, 8, 1022.
应用
Synthesis of Bis-indolyl Methane Derivatives Using PFPAT Catalyst
Typical Procedure:
A mixture of aldehyde (1 mmol), indole (2 mmol) dissolved in acetonitrile (3 mL), and PFPAT (10 mol%) is stirred for appropriate reaction time. The reaction is monitored by TLC. The organic phase is washed with 1 M NaOH aqueous solution (1 mL). The separated organic phase is evaporated under reduced pressure to give a crude product, which is purified by distillation or by column chromatography (hexane–ethyl acetate).
A mixture of aldehyde (1 mmol), indole (2 mmol) dissolved in acetonitrile (3 mL), and PFPAT (10 mol%) is stirred for appropriate reaction time. The reaction is monitored by TLC. The organic phase is washed with 1 M NaOH aqueous solution (1 mL). The separated organic phase is evaporated under reduced pressure to give a crude product, which is purified by distillation or by column chromatography (hexane–ethyl acetate).
References
参考文献
技术文章
[TCIMAIL No.138] Useful Ammonium Triflate Catalysts for Esterification[研究论文] 使用PFPAT催化剂合成双吲哚甲烷衍生物
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