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CAS RN: 198-55-0 | 产品编码: P1629
产品编码 | P1629 |
纯度/分析方法 ![]() |
>99.0%(GC) |
分子式/分子量 | C__2__0H__1__2 = 252.32 |
外观与形状(20°C) | 固体 |
储存温度 ![]() |
室温 (15°C以下阴凉干燥处) |
储存在惰性气体下 | 存放于惰性气体之中 |
应避免的情况 | 空气 |
包装和容器 ![]() |
1G-Glass Bottle with Plastic Insert (查看图片) |
CAS RN | 198-55-0 |
Reaxys-RN | 1911335 |
PubChem物质ID | 87558356 |
SDBS (AIST Spectral DB) | 3151 |
Merck Index (14) | 7184 |
MDL编号 | MFCD00004142 |
技术规格
Appearance | Light yellow to Brown powder to crystaline |
Purity(GC) | min. 99.0 % |
NMR | confirm to structure |
物性(参考值)
熔点 | 278 °C |
GHS
相关法规
RTECS# | SE3794000 |
运输信息
HS编码* | 2902.90-000 |
应用
CHF2-sulfonium salt for Photo-catalytic Difluoromethylations
A Schlenk tube is charged with an acetonitrile (5.0 mL) solution of an aromatic alkene (0.250 mmol), D5630 (190 mg, 0.500 mmol), perylene (3.2 mg, 0.0127 mmol) and water (4.5 mg, 0.250 mmol) under a nitrogen atmosphere. The mixture is degassed by freeze-pump-thaw cycles. The Schlenk tube is placed at 2-3 cm away from blue LED lamps (λ = 425 ± 15 nm) in a water bath. The mixture is stirred for 6-12 h at room temperature under visible light irradiation. After the reaction, water (15 mL) is added and resulting suspension is extracted with dichloromethane (15 mL × 3). The combined organic layer is dried over sodium sulfate , and concentrated under reduced pressure. The purification by column-chromatography and repreciptitation affords the desired products.
References
- Metal-free Di- and Tri-fluoromethylation of Alkenes Realized by Visible-light-induced Perylene Photoredox Catalysis
应用
Organic Electroluminescent Material
References
- Electroluminescence in organic films with three-layer structure
- C. Adachi, S. Tokito, T. Tsutsui, S. Saito, Jpn. J. Appl. Phys. Part 2 1988, 27, L269.
- Electroluminescence of epitaxial perylene films
- Reduction of molecular aggregation and its application to the high-performance blue perylene-doped organic electroluminescent device
应用
Organic Semiconductor Material
References
- Energy gaps in organic semiconductors derived from electrochemical data
- Epitaxial growth of a crystalline organic semiconductor:? Perylene/Cu{110}
- Organic field-effect transistors using perylene
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