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CAS RN: | 产品编码: T0690
TMS-HT Kit (=HMDS and TMCS in Anhydrous Pyridine) 1 mL × 8 / Reaction vial, capacity 2 mL × 8 [Trimethylsilylating Reagent, for OH compounds]
技术规格
Appearance | Colorless to Light orange to Yellow clear liquid to cloudy liquid |
Effect test of TMS derivatization | Effective as derivatization agent D-(+)-Glucose |
High boiling impurity of Silylation agent | No impurity higher than Isopropyl myristate(50 ppm) after 5 min + hold up time |
物性(参考值)
GHS
象形图 |
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信号词 | Danger |
危险性说明 | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H361 : Suspected of damaging fertility or the unborn child. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H373 : May cause damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H410 : Very toxic to aquatic life with long lasting effects. H225 : Highly flammable liquid and vapor. |
防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground and bond container and receiving equipment. P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take action to prevent static discharges. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 : Collect spillage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
相关法规
运输信息
UN编号 | UN2924 |
类别 | 3 / 8 |
包装类别 | II |
HS编码* | 3822.19-000 |
应用
Trimethylsilylating Reagent for GC Derivatization
Experimental procedure: TMS-HT (1 mL) is added to a sample (ca. 1 mg) in a vessel (preferably a vial of 2 mL capacity), and then it is sealed and shaken (crystals of ammonium chloride are precipitated). The supernatant is injected into the GC column. In some cases, it is needed to heat to complete the reaction.
References
- Preparation and Gas Chromatography of the Trimethylsilyl Derivatives of Resin Acids and the Corresponding Alcohols
- Gas Chromatography of Aromatic Acids
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