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CAS RN: 49591-20-0 | Product Number: B2188

N-tert-Butylbenzenesulfinimidoyl Chloride [Oxidizing Reagent]


Purity: >80.0%(NMR)
Synonyms:
  • N-tert-Butylphenylsulfinimidoyl Chloride
Documents:
1G
$119.00
14   10  
5G
$361.00
≥20  Contact Us

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Product Number B2188
Purity / Analysis Method >80.0%(NMR)
Molecular Formula / Molecular Weight C__1__0H__1__4ClNS = 215.74  
Physical State (20 deg.C) Solid
Storage Temperature <0°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive,Heat Sensitive
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 49591-20-0
Reaxys Registry Number 8678624
PubChem Substance ID 87565048
MDL Number

MFCD03093621

Specifications
Appearance Light yellow to Brown powder to lump
Purity(NMR) min. 80.0 atom%
Functionality test to pass test
Properties (reference)
Solubility (slightly sol. in) Toluene
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dusts or mists.
P234 : Keep only in original container.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P390 : Absorb spillage to prevent material damage.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN3261
Class 8
Packing Group III
H.S.code* 2930.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Effective Oxidant for the Alcohol Oxidation and β-Alkyl Enone Synthesis

B2188

One-pot β-substitution of the enone2): To a stirred solution of CuCN (29.9 mg, 0.33 mmol) in diethyl ether (2 mL) is added a solution of methyllithium in diethyl ether (0.98 mol/L, 0.63 mL, 0.62 mmol) at -78 °C, and the mixture is stirred for 10 min at 0 °C. Then, a solution of 4-phenyl-2-cyclohexene-1-one (49.6 mg, 0.28 mmol) in diethyl ether (1.5 mL) is added at -78 °C, and the reaction mixture is stirred for 20 min at -23 °C. Next, a solution of 1 (183 mg, 0.85 mmol) in diethyl ether (1 mL) is added at -78 °C, and the mixture is stirred for 30 min. The reaction is quenched by adding 10% NH4OH in saturated NH4Cl (5 mL) at -78 °C, and resulting mixture is extracted with diethyl ether three times. The combined extracts are washed with water and brine, dried over anhydrous Na2SO4, filtered and concentrated. The crude product is purified by silica gel chromatography (hexanes:diethyl ether) to afford 3-methyl-4-phenyl-2-cyclohexene-1-one (48.8 mg, 0.26 mmol, 93%) as a colorless oil.

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