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CAS RN: 174501-64-5 | Product Number: B2320

1-Butyl-3-methylimidazolium Hexafluorophosphate


Purity: >98.0%(HPLC)(N)
Synonyms:
  • BMIMPF6
Documents:
5G
$55.00
8   Contact Us
25G
$157.00
≥20  ≥20 

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* The storage conditions are subject to change without notice.


Product Number B2320
Purity / Analysis Method >98.0%(HPLC)(N)
Molecular Formula / Molecular Weight C__8H__1__5F__6N__2P = 284.19  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Hygroscopic
CAS RN 174501-64-5
Reaxys Registry Number 8026031
PubChem Substance ID 87565152
Merck Index (14) 1581
MDL Number

MFCD03093295

Specifications
Purity(HPLC) min. 98.0 area%
Purity(with Total Nitrogen) min. 98.0 %
Properties (reference)
Specific Gravity (20/20) 1.37
Refractive Index 1.41
Solubility in water Completely miscible
Solubility (insoluble in) Toluene
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
H.S.code* 2933.29-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Synthesis of quinolines via Friedländer annulation in an ionic liquid

Typical procedure: A mixture of 2-aminobenzophenone (197 mg), ethyl acetoacetate (169 mg) and CAN (27 mg) in BMIMPF6 (2 mL) ionic liquid is stirred at 60 °C for 30 min. Subsequently, the reaction mixture is extracted with EtOAc and dried over MgSO4. After filtration, the mixture is concentrated under reduced pressure and the residue is purified by chromatography on silica gel (eluent: hexane/EtOAc = 3/1) to give the desired quinoline (268 mg, 92 %). The remaining ionic liquid is dried at 80 °C under reduced pressure and reused in subsequent runs.

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