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CAS RN: 19740-72-8 | Product Number: D5365
Diisopropyl Hydrazine-1,2-dicarboxylate
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Purity: >98.0%(GC)
Synonyms:
- Hydrazine-1,2-dicarboxylic Acid Diisopropyl Ester
Documents:
| Size | Unit Price | Same Day | 2-3 Business Days |
|---|---|---|---|
| 200MG |
$117.00
|
4 | 4 |
| 1G |
$404.00
|
22 | 1 |
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| Product Number | D5365 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__8H__1__6N__2O__4 = 204.23 |
| Physical State (20 deg.C) | Solid |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 19740-72-8 |
| Reaxys Registry Number | 1872653 |
| PubChem Substance ID | 354335450 |
| MDL Number | MFCD19443326 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(GC) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 108 °C |
| Solubility (soluble in) | Methanol |
GHS
Related Laws:
Transport Information:
| H.S.code* | 2928.00-000 |
Application
Organocatalyst for Photocatalytic Esterification
Experimental procedure:
A mixture of 1 (0.180 mmol), 2 (0.150 mmol), triphenylphosphine (0.30 mmol), diisopropyl hydrazine-1,2-dicarboxylate (0.0150 mmol), TARF3-CH3 (0.0150 mmol), phenylsilane (0.30 mmol) and activated MS 4A (150 mg) in CH3CN (2 mL) is bubbled with oxygen (2 min) and then is heated at 50 °C under O2 (balloon) under irradiation with blue LEDs (450 nm, 1 W LED) for 24 h. Then, the reaction mixture is filtered and the solvent is evaporated. The residue is purified by flash chromatography (silica gel, hexane:EtOAc = 20:1 or CHCl3) to give 3 (65% yield).
A mixture of 1 (0.180 mmol), 2 (0.150 mmol), triphenylphosphine (0.30 mmol), diisopropyl hydrazine-1,2-dicarboxylate (0.0150 mmol), TARF3-CH3 (0.0150 mmol), phenylsilane (0.30 mmol) and activated MS 4A (150 mg) in CH3CN (2 mL) is bubbled with oxygen (2 min) and then is heated at 50 °C under O2 (balloon) under irradiation with blue LEDs (450 nm, 1 W LED) for 24 h. Then, the reaction mixture is filtered and the solvent is evaporated. The residue is purified by flash chromatography (silica gel, hexane:EtOAc = 20:1 or CHCl3) to give 3 (65% yield).
References
- Photocatalytic esterification under Mitsunobu reaction conditions mediated by flavin and visible light
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