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CAS RN: 7425-55-0 | Product Number: E1199

Ethyl 2-Iodo-2-methylpropionate

Purity: >94.0%(GC)
  • 2-Iodo-2-methylpropionic Acid Ethyl Ester
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* The storage conditions are subject to change without notice.

Product Number E1199
Purity / Analysis Method >94.0%(GC)
Molecular Formula / Molecular Weight C__6H__1__1IO__2 = 242.06  
Physical State (20 deg.C) Liquid
Storage Temperature <0°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive,Heat Sensitive
CAS RN 7425-55-0
Reaxys Registry Number 1853586
PubChem Substance ID 354333692
Appearance Light yellow to Brown clear liquid
Purity(GC) min. 94.0 %
Properties (reference)
Flash point 79 °C
Specific Gravity (20/20) 1.55
Refractive Index 1.49
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H227 : Combustible liquid.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P403 + P235 : Store in a well-ventilated place. Keep cool.
Related Laws:
Transport Information:
H.S.code* 2915.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Alkyl Iodide Initiators for Organocatalyzed Living Radical Polymerization

General Scheme of Organocatalyzed Living Radical Polymerization1-4)

Goto et al. have reported that alkyl iodides are efficient initiators for organocatalyzed living radical polymerization which is a new family of living radical polymerization. Organic amines and organic salts are used as catalysts.1-4) Low polydispersity and metal free polymers can be obtained by using this method.
Ranges of Effective Alkyl Iodides in the Polymerizations of Methyl Methacrylate (MMA) and Butyl Acrylate (BA)1)

These alkyl iodides are effective initiators in methyl methacrylate (MMA) [M0087] and butyl acrylate (BA) [A0142] polymerizations using tributylmethylphosphonium iodide (BMPI) [M1455] or tetrabutylammonium iodide (BNI) [T0057] as a catalyst. Low-polydispersity polymers are obtainable.1)


PubMed Literature

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