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CAS RN: 1450-14-2 | Product Number: H0638

Hexamethyldisilane


Purity: >98.0%(GC)
Synonyms:
Documents:
10ML
$59.00
≥20  ≥20 
100ML
$270.00
≥20  ≥20 

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* The storage conditions are subject to change without notice.


Product Number H0638
Purity / Analysis Method >98.0%(GC)
Molecular Formula / Molecular Weight C__6H__1__8Si__2 = 146.38  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 1450-14-2
Reaxys Registry Number 1633463
PubChem Substance ID 87571012
SDBS (AIST Spectral DB) 18249
MDL Number

MFCD00008258

Specifications
Appearance White or Colorless to Light yellow powder to lump to clear liquid
Purity(GC) min. 98.0 %
Properties (reference)
Melting Point 13 °C
Boiling Point 113 °C
Flash point -9 °C
Specific Gravity (20/20) 0.73
Refractive Index 1.42
Solubility in water Practically insoluble
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H319 : Causes serious eye irritation.
H317 : May cause an allergic skin reaction.
H335 : May cause respiratory irritation.
H413 : May cause long lasting harmful effects to aquatic life.
H225 : Highly flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P273 : Avoid release to the environment.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
RTECS# JM9170000
Transport Information:
UN Number UN1993
Class 3
Packing Group II
H.S.code* 2931.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
A Novel Cyanation Reaction of Arenes Using Acetonitrile as a Cyano Source

A0060

[Experimental Procedure]
Cyanation of Cumene (R=i-Pr) : An oven-dried Schlenk tube equipped with a magnetic stir bar is evacuated and backfilled with O2 three times. Cumene (0.5 mmol), N-iodosuccinimide (NIS) (1.05 eq., 0.525 mmol), Cu(ClO4)2·6H2O (20 mol%, 0.1 mmol), acetonitrile (1.2 mL) are added into the tube and the reaction is stirred at 150°C for 1 hour. The reaction mixture is allowed to cool down. Under O2, 1,10-phenanthroline (20 mol%, 0.1 mmol), TEMPO free radical (2 eq., 1 mmol), hexamethyldisilane (1 eq., 0.5 mmol) are added into the reaction mixture. The reaction is then heated up to 150°C for 2.5 days under O2. After completion, the insoluble is removed by filtration. The filtrate is concentrated under vacuo and the residue is purified by column chromatography on silica gel using EtOAc / petroleum ether to give the corresponding p- or o-cyanated cumenes as a yellow liquid (65 mg, 90% yield, p:o = 6:1).

References


Application
Stereospecific deoxygenation

References


PubMed Literature


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