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CAS RN: 407-25-0 | Product Number: T0433
Trifluoroacetic Anhydride
Purity: >98.0%(GC)
Synonyms:
- TFAA
Product Documents:
Size | Unit Price | Same Day | 2-3 Business Days |
---|---|---|---|
20ML |
$29.00
|
6 | Contact Us |
100ML |
$95.00
|
34 | Contact Us |
400ML |
$284.00
|
6 | ≥40 |
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* The storage conditions are subject to change without notice.
Product Number | T0433 |
Purity / Analysis Method | >98.0%(GC) |
Molecular Formula / Molecular Weight | C__4F__6O__3 = 210.03 |
Physical State (20 deg.C) | Liquid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Moisture Sensitive |
CAS RN | 407-25-0 |
Reaxys Registry Number | 746197 |
PubChem Substance ID | 87576385 |
SDBS (AIST Spectral DB) | 935 |
MDL Number | MFCD00000416 |
Specifications
Appearance | Colorless to Almost colorless clear liquid |
Purity(GC) | min. 98.0 % |
NMR | confirm to structure |
Properties (reference)
Boiling Point | 40 °C |
Specific Gravity (20/20) | 1.50 |
GHS
Pictogram | |
Signal Word | Danger |
Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H412 : Harmful to aquatic life with long lasting effects. H290 : May be corrosive to metals. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P273 : Avoid release to the environment. P270 : Do not eat, drink or smoke when using this product. P234 : Keep only in original container. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P390 : Absorb spillage to prevent material damage. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
Related Laws:
RTECS# | AJ9800000 |
Transport Information:
UN Number | UN3265 |
Class | 8 |
Packing Group | I |
H.S.code* | 2915.90-000 |
Application
Trifluoroacetylating Reagent for GC Derivatization
Experimental procedure: A sample (1-5 mg) is dissolved in solvent such as acetone or dichloromethane (0.5 mL), and trifluoroacetic anhydride (200 μL) is added. The mixture is allowed to react for 20-30 min at room temperature (or heated to 40 °C if necessary). After removing excess reagent and solvent by N2-blowing, the residue is dissolved in acetone or other solvents to be used as a GC sample.
References
- Polar-liquid, derivatized cyclodextrin stationary phases for the capillary gas chromatography separation of enantiomers
Application
Perfluoroalkylation using Perfluoro Acid Anhydrides
References
- Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source
PubMed Literature
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