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CAS RN: 719-98-2 | Product Number: T3143

N-(Trifluoromethylthio)phthalimide


Purity: >98.0%(GC)
Synonyms:
Documents:
1G
$189.00
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5G
$658.00
≥20  3  

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Product Number T3143
Purity / Analysis Method >98.0%(GC)
Molecular Formula / Molecular Weight C__9H__4F__3NO__2S = 247.19  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 719-98-2
Reaxys Registry Number 1464619
PubChem Substance ID 253662481
Specifications
Appearance White to Almost white powder to crystal
Purity(GC) min. 98.0 %
Melting point 111.0 to 115.0 °C
Properties (reference)
Melting Point 113 °C
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
H.S.code* 2930.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Catalytic Trifluoromethylthiolation Using N-(Trifluoromethylthio)phthalimide

T3143

Typical Procedure (Reaction of 1 with boronic acids)3):
CuCl (4.0 mg, 0.04 mmol, 10 mol%), dry boronic acid (0.4 mmol, 1.0 eq.), dry K2CO3 (111 mg, 0.8 mmol, 2.0 eq.), 2,2’-bipyridine (12.5 mg, 0.08 mmol, 20 mol%) and N-(trifluoromethylthio)phthalimide (103.8 mg, 0.42 mmol, 1.05 eq.) are placed into an oven-dried Schlenk tube equipped with a stirring bar. The tube is sealed with a rubber stopper, evacuated and back-filled with dry argon (three times). Dry, freshly distilled and degassed DME is added by a syringe and the reaction mixture is stirred at 45 °C for 18 h. The reaction mixture is cooled to room temperature, diluted with diethyl ether (5 mL), and filtered through a short plug of silica, eluting with additional diethyl ether (50 mL). The filtrate is concentrated; pentane (10 mL) is added and concentrated again for removing residual DME. The resulting residue is purified by chromatography (pentane―diethyl ether) to provide the desired product.

References


PubMed Literature


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