Maximum quantity allowed is 999
CAS RN: 811-68-7 | Product Number: S0977
Silver(I) Trifluoromethanethiolate

Purity: >95.0%(T)
- Trifluoromethanethiol Silver(I) Salt
Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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1G |
NT$5,208
|
2 | ≥60 | Contact Us | |
5G |
NT$18,228
|
12 | ≥40 | Contact Us |
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Product Number | S0977 |
Purity / Analysis Method | >95.0%(T) |
Molecular Formula / Molecular Weight | CAgF__3S = 208.93 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Light Sensitive,Air Sensitive |
Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
CAS RN | 811-68-7 |
Reaxys Registry Number | 4151922 |
PubChem Substance ID | 354333285 |
MDL Number | MFCD25563234 |
Appearance | White to Light yellow to Light red powder to crystal |
Purity(Precipitation Titration) | min. 95.0 % |
Solubility in water | Insoluble |
Solubility (slightly sol. in) | Methanol |
H.S.code* | 2843.29-000 |
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Used Chemicals
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Procedure
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Silver(I) trifluoromethanethiolate (907 mg, 4.34 mmol), tetrabutylammonium iodide (4.81 g, 13.0 mmol) and 4-methoxybenzyl alcohol (200 mg, 1.45 mmol) were dissolved in toluene (15 mL) and stirred at 80 °C for 19 hours. The reaction mixture was cooled to room temperature and filtered through a plug of silica gel (eluted with ethyl acetate). The solvent was removed under reduced pressure and the residue was purified by silica gel column chromatography (hexane) to give (4-methoxybenzyl)(trifluoromethyl)sulfane as a colourless oil (216 mg, 67% yield).
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Experimenter’s Comments
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The reaction mixture was monitored by NMR.
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Analytical Data
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(4-Methoxybenzyl)(trifluoromethyl)sulfane
1H NMR (270 MHz, CDCl3); δ 7.26 (d, 2H, J = 8.4 Hz), 6.86 (d, 2H, J = 8.4 Hz), 4.09 (s, 2H), 3.80 (s, 3H).
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Lead Reference
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- Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide
References
- 1)Pd-Catalyzed Synthesis of Ar-SCF3 Compounds under Mild Conditions
- 2)Silver-Mediated Radical Aryltrifluoromethylthiolation of Activated Alkenes
- 3)Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide
- 4)Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I)Trifluoromethanethiolate and an Inorganic Iodide
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