Maximum quantity allowed is 999
Please select the quantity
CAS RN: 181934-29-2 | Product Number: T3272
1-[(Trimethylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one
×
![]()
×
![1-[(Trimethylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "1-[(Trimethylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one")
Purity: >98.0%(T)
Synonyms:
- TMS-EBX
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
NT$6,090
|
19 | 0 | Contact Us | |
| 5G |
NT$19,362
|
5 | 0 | Contact Us |
* The above prices include freight cost, customs, and other charges to the destination except for products that need to be shipped by sea or dry ice. For details, please contact
our distributor
in Taiwan to order our product.
* The storage conditions are subject to change without notice.
| Product Number | T3272 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__1__2H__1__3IO__2Si = 344.22 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Heat Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 181934-29-2 |
| Reaxys Registry Number | 7707098 |
| PubChem Substance ID | 354333836 |
Specifications
| Appearance | White to Light yellow to Light orange powder to crystal |
| Purity(Precipitation Titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 140 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| H.S.code* | 2934.99-000 |
Application
An Ethynylating Agent
Experimental procedure1): A solution of 1 (89 mg, 0.40 mmol, 1.0 eq.) and TMS-EBX (179 mg, 0.520 mmol, 1.3 eq.) in dried THF (6 mL) is stirred at -78 °C for 5 min under nitrogen. After this period of time, TBAF (1 mol/L in THF, 1.3 eq.) is added and mixture is vigorously stirred for 1 h at -78 °C. The reaction mixture is quenched with deactivated silica gel and the solvent is evaporated under reduced pressure. The product is purified by flash chromatography (SiO2, Hexane:EtOAc = 8:1) to afford 2 (92 mg, 0.37 mmol, 93%) as yellow oil.
References
- 1)Ethynyl-1,2-benziodoxol-3(1H)-one (EBX): An Exceptional Reagent for the Ethynylation of Keto, Cyano, and Nitro Esters
- 2)A Highly Chemoselective and Practical Alkynylation of Thiols
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Useful Hypervalent Iodine Compound for the Introduction of an Ethynyl GroupProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.