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CAS RN: 1648825-53-9 | 產品號碼: P2420
補充產品訊息:
PhenoFluor™ is a trademark of SciFluor Life Sciences, Inc.
| 產品號碼 | P2420 |
| 分子式 / 分子量 | C__2__7H__3__6Cl__2N__2·xCsF |
| 外觀與形狀(20°C) | Solid |
儲存條件
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Moisture Sensitive |
包裝和容器
|
1G-Glass Bottle with Plastic Insert (閲覽圖片) |
| CAS RN | 1648825-53-9 |
| PubChem Substance ID | 354334397 |
產品規格
| Appearance | White to Almost white powder to crystal |
| Content | 30.0 to 32.0% [as 2-Chloro-1,3-bis(2,6-diisopropylphenyl)-1H-imidazolium Chloride] |
| NMR | confirm to structure |
性質
| 熔點 | 229 °C |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P405 : Store locked up. |
相關法規
運輸資料
| UN編號 | UN2923 |
| 類別 | 8 / 6.1 |
| 包裝類別 | III |
| HS編碼* | 2933.29-000 |
Application
PhenoFluorTM Mix: Stable Agent for Deoxyfluorination

Experimental procedure: A mixture of 4-(methylsufonyl)phenol (88.8 mg, 0.500 mmol) and PhenoFluorTM Mix (1.10 g) in toluene (5.0 mL) is stirred at 23 °C for 30 min, then at 110 °C for 24 h. Purification by flash silica gel column chromatography (hexanes:EtOAc = 9:1 - 7:3) affords the desired compound as a colorless solid (86.4 mg, 99% yield).
References
- PhenoFluorMix: Practical Chemoselective Deoxyfluorination of Phenols
文檔
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