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Easy-to-Handle Trifluoromethylating Agent for Multiple Uses

5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Product

T4037
5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

This product is manufactured pursuant to a license with Studiengesellschaft Kohle gGmbH.
This product is intended to be used for research and development purposes only. If you need to order for commercial use or larger quantities, please contact us.

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Advantages

  • Air-stable and easy-to-handle solid powder
  • Highly reactive in a wide range of reactions

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Applications 1,2)

Cross-Coupling Reaction

Cross-Coupling Reaction using 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Nucleophilic Trifluoromethylation

Nucleophilic Trifluoromethylation using 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Trifluoromethylation of Thiols

Trifluoromethylation of Thiols using 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Radical Trifluoromethylation

Radical Trifluoromethylation using 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Electrophilic Trifluoromethylation

Electrophilic Trifluoromethylation using 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

Hydrotrifluoromethylation of Olefins

Hydrotrifluoromethylation of Olefins using 5-(Trifluoromethyl)-5H-thianthren-5-ium Trifluoromethanesulfonate

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References

  1. 1) Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3, and CF3 Reactivity
  2. 2) α-Thianthrenium Carbonyl Species: The Equivalent of an α-Carbonyl Carbocation

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