Phosphine Ligand Immobilizable on Silica and Metal Oxide Surfaces

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Advantages

• Enables chemical immobilization on silica and metal oxide surfaces by silane coupling treatment.
• Bidentate coordination allows complexation with various metals.
• The immobilized carriers are expected to be applied to continuous flow synthesis.

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Applications

Highly active allylation catalyst with the synergistic effect of DABCO and Palladium ^1,2)

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Reactions Using The Immobilized Carriers

Allylation using SiO₂/DABCO/PP-Pd ^1,2)

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Synthesis of aromatic polyamides using palladium catalyst immobilized on magnetic particles ³⁾

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Related Products

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Related Product Category Pages

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Product Brochure

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References

1. 1) Co-Immobilization of a Palladium–Bisphosphine Complex and Strong Organic Base on a Silica Surface for Heterogeneous Synergistic Catalysis
   • K. Motokura, K. Saitoh, H. Noda, Y. Uemura, W. Chun, A. Miyaji, S. Yamaguchi, T. Baba, ChemCatChem 2016, 8, 331.
2. 2) A Pd–bisphosphine complex and organic functionalities immobilized on the same SiO₂ surface: detailed characterization and its use as an e cient catalyst for allylation
   • K. Motokura, K. Saitoh, H. Noda, W. Chun, A. Miyaji, S. Yamaguchi, T. Baba, Catal. Sci. Technol. 2016, 6, 5380.
3. 3) Synthesis of new uorinated aromatic poly (ether ketone amide)s containing cardo structures by a heterogeneous palladium-catalyzed carbonylative polycondensation
   • L. Liu, F. Zou, R. Zhang, M. Cai, Polym. Adv. Technol. 2018, 30, 58.

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