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Photo- and Thermal-Acid Generators with Organogallium Anion

Photo- or thermal-acid generators containing the counter anion of organogallium (Ga(C6F5)4−) can generate a strong acid upon decomposition, comparable in strength to hexafluoroantimonic acid (HSbF6). On the other hand, compared to SbF6 salts, Ga(C6F5)4 salts are less likely to produce hydrogen fluoride (HF), resulting in lower metal corrosivity to surrounding materials. Additionally, Ga(C6F5)4 salts offer the advantage of lower discoloration of cured resins under high-temperature heating. Furthermore, Ga(C6F5)4 salts exhibit lower toxicity than SbF6 salts.

[1,1'-Biphenyl]-4-yl[4-[[1,1'-biphenyl]-4-ylthio]phenyl](phenyl)sulfonium Tetrakis(pentafluorophenyl)gallate (contains isomer)
4-Isopropylphenyl(p-tolyl)iodonium Tetrakis(pentafluorophenyl)gallate
Benzyl(4-hydroxyphenyl)methylsulfonium Tetrakis(pentafluorophenyl)gallate

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Related Products: Sulfonium Salt-Type Photo-acid Generators

We offer sulfonium salts with various counter anions.
We can also synthesize sulfonium salts not listed in our product catalog, so please feel free to contact us.

Sulfonium Salt-Type Photo-acid Generators
T4012
Triphenylsulfonium Hexafluoroantimonate
T4013
Triphenylsulfonium Hexafluorophosphate
T1608
Triphenylsulfonium Tetrafluoroborate
T2180
Triphenylsulfonium Trifluoromethanesulfonate
T3038
Triphenylsulfonium Nonafluoro-1-butanesulfonate
T4024
Triphenylsulfonium 10-Camphorsulfonate
T1609
Triphenylsulfonium Bromide
T4025
Triphenylsulfonium Chloride
D6256
Diphenyl[4-(phenylthio)phenyl]sulfonium Trifluorotris(pentafluoroethyl)phosphate (ca. 50% in Propylene Carbonate)
D6261
Diphenyl[4-(phenylthio)phenyl]sulfonium Trifluorotris(pentafluoroethyl)phosphate
D6257
Diphenyl[4-(phenylthio)phenyl]sulfonium Tetrakis(pentafluorophenyl)borate (ca. 40% in Propylene Carbonate)
D6258
Diphenyl[4-(phenylthio)phenyl]sulfonium Tetrakis(pentafluorophenyl)borate
D5952
Diphenyl[4-(phenylthio)phenyl]sulfonium Hexafluoroantimonate
D6259
Diphenyl[4-(phenylthio)phenyl]sulfonium Hexafluoroantimonate (ca. 50% in Propylene Carbonate)
D5990
Diphenyl[4-(phenylthio)phenyl]sulfonium Hexafluorophosphate
D6260
Diphenyl[4-(phenylthio)phenyl]sulfonium Hexafluorophosphate (ca. 50% in Propylene Carbonate)
B6631
[1,1'-Biphenyl]-4-yl[4-[[1,1'-biphenyl]-4-ylthio]phenyl](phenyl)sulfonium Tetrakis(perfluorophenyl)borate (contains isomer)
B7057
[1,1'-Biphenyl]-4-yl[4-[[1,1'-biphenyl]-4-ylthio]phenyl](phenyl)sulfonium Tetrakis(pentafluorophenyl)gallate (contains isomer)
B6324
(Thiodi-4,1-phenylene)bis(diphenylsulfonium) Bis(hexafluorophosphate)
T4222
(9-Oxo-9H-thioxanthen-2-yl)[4-[(9-oxo-9H-thioxanthen-2-yl)thio]phenyl](phenyl)sulfonium Trifluorotris(perfluoroethyl)phosphate(V)
T4223
(9-Oxo-9H-thioxanthen-2-yl)[4-[(9-oxo-9H-thioxanthen-2-yl)thio]phenyl](phenyl)sulfonium Tetrakis(perfluorophenyl)borate

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Related Products: Iodonium Salt-Type Photo-acid Generators

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Related Products: Photosensitizers

Iodonium salts are easily used in combination with photosensitizers, so we also offer photosensitizers as related products.
In addition to the photosensitizers listed below, we also have many other products available, so please contact us if you require more information.

D4515
9,10-Dibutoxyanthracene
I0678
2-Isopropylthioxanthone
C2302
Curcumin (Synthetic)
C0014
(±)-Camphorquinone
M0631
7-Diethylamino-4-methylcoumarin
B0139
4,4'-Bis(diethylamino)benzophenone
P0106
Phenothiazine
P1104
Pyrene

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