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CAS RN: 866081-62-1 | Product Number: B5301
(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
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Purity: >98.0%(HPLC)
Synonyms:
- (R,R)-QuinoxP*
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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|
|---|---|---|---|---|---|
| 100MG |
$197.00
|
9 | 5 | Contact Us |
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| Product Number | B5301 |
Purity / Analysis Method 
|
>98.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__1__8H__2__8N__2P__2 = 334.38 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container
|
100MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 866081-62-1 |
| Reaxys Registry Number | 10182166 |
| PubChem Substance ID | 354334700 |
| MDL Number | MFCD10565649 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Melting point | 100.0 to 104.0 °C |
| Specific rotation [a]20/D | -48.0 to -53.0 deg(C=1, CHCL3) |
Properties (reference)
| Melting Point | 102 °C |
| Specific Rotation | -52° (C=1,CHCl3) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H413 : May cause long lasting harmful effects to aquatic life. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| H.S.code* | 2933.99-000 |
Application
Dynamic Kinetic Resolution using a Palladium / QuinoxP* Complex
References
- 1)A Rational Pre-catalyst Design for Bis-Phosphine Mono-oxide Palladium Catalyzed Reactions
- 2)Enantioselective Synthesis of Hemiaminals via Pd-Catalyzed C?N Coupling with Chiral Bisphosphine Mono-oxides
- 3)Searching for Practically Useful P-Chirogenic Phosphine Ligands
Application
Copper Catalyzed Asymmetric Conjugate Addition
References
- Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
Application
Rhodium Catalyzed Enantioselective Hydroacylation of Acrylamide Derivatives
References
- Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
Application
Ruthenium Complex Catalyzed Asymmetric Hydrogenation
References
- t-Bu-QuinoxP* Ligand:? Applications in Asymmetric Pd-Catalyzed Allylic Substitution and Ru-Catalyzed Hydrogenation
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
PubMed Literature
Product Articles
[Research Articles] Dynamic Kinetic Resolution using a Palladium / QuinoxP* ComplexProduct Documents (Note: Some products will not have analytical charts available.)
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