Chiral Bis(oxazoline) Ligands

No.115

B2218: (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine (1a)
B2217: (R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine (1b)
B2220: (S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine (2a)
B2219: (R,R)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine (2b)
I0582: (S,S)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline) (3a)
D2823: (R,R)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline) (3b)
I0567: (S,S)-(-)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline) (4)

References

1)Enantioselective hydrosilylation of ketones
- H. Nishiyama, H. Sakaguchi, T. Nakamura, M. Horihata, M. Kondo, K. Itoh, Organometallics 1989, 8, 846.
- H. Nishiyama, M. Kondo, T. Nakamura, K. Itoh, Organometallics 1991, 10, 500.
2)Asymmetric ring opening of meso epoxides
- S. E. Schaus, E. N. Jacobsen, Org. Lett. 2000, 2, 1001.
3)Enantioselective aziridination of olefins
- D. A. Evans, M. M. Faul, M. T. Bilodeau, B. A. Anderson, D. M. Barnes, J. Am. Chem. Soc. 1993, 115, 5328.
4)Asymmetric syntheses with chiral bis(oxazoline) ligands

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