Home > Exhibitions / Brochures Download > Quarterly Printed Magazine "TCIMAIL" > BackNumbers 2004 > Useful Silyl Compound

Useful Silyl Compound

Silyl compound 1 reacts with iodobenzene diacetate in the presence of trifluoromethanesulfonic acid to give hypervalent iodine compound 2. Treatment of compound 2 with tetrabutylammonium fluoride at room temperature generates benzyne 3, which in turn give several types of cyclic compounds in the presence of a trapping agent such as furan.1) Since the generation of 3 from 1 is carried out under mild conditions, this methodology can be utilized in various fields.

The reaction of 1 with 1,2-bis(trichlorotelluro)benzene can also provide telluranthene 4.2)

References

The prices are subject to change without notice. Please confirm the newest price by our online catalog before placing an order.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.