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Enantioselective Epoxidation

Katsuki et al. have reported that the chiral salen-Mn(III) complex 1 is useful as a catalyst for enantioselective epoxidation of conjugated cis-olefins.1 Complex 1 is oxidized with iodosobenzene as co-oxidant to generate oxo(salen)-Mn(V) complex 2, which then reacts with conjugated cis-olefins to yield chiral epoxides 3 with high enantioselectivity.

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