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Useful Acceptor-Type Organic Semiconductor Building Blocks

Naphtho[1,2-c:5,6-c']bis([1,2,5]thiadiazole) (NTz) structures (13) are useful electron-deficient type building blocks for organic semiconductors. Some donor–acceptor conjugated polymers containing the NTz structures exhibited better power conversion efficiency (PCE) compared with widely used 2,1,3-benzothiadiazole-based polymers in organic photovoltaic devices.1,2) In addition, several conjugated polymers exhibiting beyond 10% PCEs were reported in 2016.3)


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