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Useful Palladium Catalyst

Sterically bulky [1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II) dichloride (1) is a complex of an electron-rich bidentate phosphine ligand and palladium(II). The large bite angle of 1 imparts high catalytic activity to the catalyst. In the Suzuki-Miyaura reaction, for example, even unactivated aryl chlorides or very sterically hindered substrates undergo reaction to give the corresponding coupling products in high yields.1) In addition, its high stability in air is one of the features of this catalyst, which increases its utility in a number of fields.


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