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A New Stable Fluorinating Reagent with Ease of Handling (Hara Reagent)

No.168(January 2016)
P2140
IF5-Pyridine-HF  (1)
IF5-Pyridine-HF (1), which was first reported by Hara et al., is a novel fluorinating reagent. 1 is a crystalline solid reagent with air stability and non-hygroscopicity which makes it easier to handle. 1 can be applied to various fluorination reactions of sulfides.1) In addition, 1 iodofluorinates alkenes with stereo- and regioselectivity.2)

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