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Chiral Ligands

Chiral ligand 1 is used for enantioselective addition of Grignard reagents to ketones which affords tertiary alcohols with high optical yields1). Furthermore, a variety of titanium complexes may be prepared from 1, and the titanium complexes are used for asymmetric allylation reactions2), asymmetric alkylation reactions3), asymmetric iodocarbocyclization reactions4), and asymmetric Diels-Alder reactions5) etc.

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