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Stable Fluorinating Reagent with Ease of Handling “FLUOLEADTM"

4-tert-Butyl-2,6-dimethylphenylsulfur trifluoride (FLUOLEADTM, 1), which was first reported by Umemoto et al., is a novel nucleophilic fluorinating reagent. Differing from other existing fluorinating reagents, such as DAST, FLUOLEADTM is a crystalline solid with high thermal stability and less fuming character, which makes it easier to handle. FLUOLEADTM fluorinates a hydroxy or carbonyl group to afford the corresponding fluorinated compounds in good yields.


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