Home >   Products   >  Advanced Search

10-Methylacridinium Perchlorate
(CAS RN:26456-05-3 Product Number:M1787)

Structure

10-Methylacridinium Perchlorate

General Information

Product Number M1787

* Please contact our distributor or us if you would like to know purchase prices in Australia that include freight cost, customs charge and other charges to the destination.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quotation" button. Please note that we cannot offer bulk quantities for some products.
* TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.

Purity/Analysis Method >98.0%(N)
Storage Temperature
M.F. / M.W. C14H12ClNO4=293.70
CAS RN 26456-05-3
Related CAS RN
MDL Number
Packaging and Container
  • Product Details
  • Safety & Regulations
  • Reference & Application

Specification

Purity(with Total Nitrogen) min. 98.0 %

References

Beilstein 20(5)8,207
Reaxys-RN 3647072
PubChem SID 87559032

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H272
  • :May intensify fire; oxidizer.
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P210
  • :Keep away from heat.
  • P220
  • :Keep and store away from clothing and other combustible materials.
  • P221
  • :Take any precaution to avoid mixing with combustibles.
  • P264
  • :Wash hands and face thoroughly after handling.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :If on skin: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
  • P501
  • :Dispose of contents and container in accordance with local, regional, national regulations (e.g. US: 40 CFR Part 261, EU:91/156/EEC, JP: Waste Disposal and Cleaning Act, etc.).

Transport Information

UN Number 1479
Class 5.1
Packing Group III

Application

Baeyer–Villiger Oxidation with 10-Methylacridinium as an Organocatalyst

Typical Procedure:
Cyclobutanone (0.5 mmol) and 10-methylacridinium perchlorate (7.4 mg, 0.025 mmol) are dissolved in CH3CN (1 mL). Hydrogen peroxide (68 μL, 30% solution in water, 0.6 mmol) is added and the mixture is irradiated with a 450 W high-pressure mercury lamp in a Pyrex® flask (λ>320 nm) at room temperature for 20 h. The course of the reaction is monitored by TLC. After completion of the reaction, solvent is evaporated in vacuum. Purification of the residue by column chromatography (silica gel, ethyl acetate/petroleum ether gradient) yields the corresponding lactone.

References

Page Top