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[4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate
(CAS RN:1868173-29-8 Product Number:F1111)

Structure

[4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate
Synonym [4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium Tosylate

General Information

Product Number F1111

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Purity/Analysis Method >97.0%(HPLC)
Storage Temperature 0-10°C
M.F. / M.W. C23H21F4IO6S=628.37
CAS RN 1868173-29-8
Related CAS RN
MDL Number

Notes

This product is commercialized in partnership with Dr. Stuart and PSU.
  • Product Details
  • Safety & Regulations
  • Reference & Application

Specification

Purity(HPLC) min. 97.0 %(total of Ion-Pair)

References

PubChem SID 354334166

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P264
  • :Wash hands and face thoroughly after handling.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :If on skin: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Transport Information

HS Number 2930.90.2900

Application

Asymmetric Diaryliodonium Tosylates Useful for Metal-free Arylations

P2412,T3622,D5145,B5269,T1110,F1111, B5573,B5269

References

Hypervalent iodine compounds usable for arylating reactions

Stuart et al. have designed and synthesized some diaryl-substituted hypervalent iodine compounds having a 1,3,5-trimethoxybenzene (TMB) moiety and an aromatic ring. In these compounds, the TMB moiety acts as a leaving group so that the other aromatic ring can be used for the aryl group introduction. Various functional groups such as cyano, nitro, fluoro, or chloro substituted aromatic TMB hypervalent iodine compounds have been reported so far. It is expected to use these compounds for transition-metal-free arylations.

References

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