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1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride
(CAS RN:250285-32-6 Product Number:D3611)


1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride
Synonym IPr·HCl

General Information

Product Number D3611

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Purity/Analysis Method >98.0%(HPLC)(T)
Storage Temperature
M.F. / M.W. C27H37ClN2=425.06
CAS RN 250285-32-6
Related CAS RN
MDL Number MFCD02684545
Packaging and Container
  • Product Details
  • Safety & Regulations


Appearance White to Light yellow to Light orange powder to crystal
Purity(HPLC) min. 98.0 area%
Purity(Nonaqueous Titration) min. 98.0 %


Reaxys-RN 8460977
PubChem SID 87560255


Signal Word Warning
Hazard Statements
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P264
  • :Wash hands and face thoroughly after handling.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Transport Information

HS Number 2933299090


Cycloaddition of CO2 to Terminal Epoxides Catalyzed by NHC–ZnBr2 System under Mild Conditions

Typical procedure (R = Ph, entry 3): An oven-dried 50 mL flask containing 1,3-bis(2,6-diisopropylphenyl)imidazolium chloride (149 mg, 0.35 mmol), K2CO3 (48 mg, 0.35 mmol) and ZnBr2 (79 mg, 0.35 mmol) is purged with CO2 under atmospheric pressure three times. Then 1,2-epoxyethylbenzene (2.1 mg, 17.5 mmol) and DMSO (10 mL) are injected into the flask, and CO2 is provided by a balloon. The reaction is stirred at 80 ºC for 24 h. After the reaction is cooled down, H2O (200 mL) is added to the reaction mixture. The mixture is extracted with CH2Cl2 (3 x 20 mL). The organic layer is filtered through a silica plug, and concentrated under vacuum to give 4-phenyl-1,3-dioxolan-2-one (2.73 mg, 95 %) as a white solid.


Esterification of α-Halo-α,β-unsaturated Aldehydes by Using a Carbene Catalyst


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