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nitro-Grela
(CAS RN:502964-52-5 Product Number:N1060)

Structure

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nitro-Grela
Synonym [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[(2-isopropoxy-5-nitrobenzylidene)]ruthenium(VI)

General Information

Product Number N1060

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Purity/Analysis Method >97.0%(HPLC)
Storage Temperature
M.F. / M.W. C31H37Cl2N3O3Ru=671.63
CAS RN 502964-52-5
Related CAS RN
MDL Number MFCD28411645
Packaging and Container

Notes

Sold in collaboration with Apeiron Synthesis.
PCT/EP2003/011222
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Specification

Purity(HPLC) min. 97.0 area%
Elemental analysis(Nitrogen) 5.90 to 6.50 %

References

Reaxys-RN 19324055
PubChem SID 354334037

Transport Information

HS Number 2843909000

Application

Nitro-Grela: A Metathesis Catalyst Applicable to Macrocycle construction

References

Nitro-Grela: A Metathesis Catalyst Applicable to Various Substrates

References

Nitro-Grela: A Ruthenium Complex Useful for Metathesis Reactions

Experimental procedure2): A mixture of 1 (25.0 mg, 69.3 μmol) and nitro-Grela (929 μg, 1.39 μmol) in CH2Cl2 (3.5 mL) is stirred at room temperature for 2 h. The mixture is concentrated to give a residue, which is subjected to column chromatography on silica gel. Elution with hexane:ethyl acetate (10:1) gives 2 (15.6 mg, 74% yield) as a colorless oil.

References

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