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Cesium Acetate
(CAS RN:3396-11-0 Product Number:C2430)

Structure

Cesium Acetate
Synonym Acetic Acid Cesium Salt

General Information

Product Number C2430

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Purity/Analysis Method >98.0%(T)
Storage Temperature
M.F. / M.W. C2H3CsO2=191.95
CAS RN 3396-11-0
Related CAS RN
MDL Number MFCD00013056
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Specification

Purity(Nonaqueous Titration) min. 98.0 %
Melting point 191.0 to 195.0 deg-C

References

Beilstein 2(3)134
Reaxys-RN 3595637
PubChem SID 125307416
EC Number 222-248-0

Transport Information

HS Number 2915290090

Application

Alcohol inversion using cesium acetate and DMAP

Typical procedure: CsOAc (12.5 g) and DMAP (160 mg) are added to the alcohol nosylate 1 (4.4g) in dry toluene (100 mL). The solution is refluxed for 8h, cooled, filtered through Celite, and concentrated under reduce pressure. The resulting slurry is diluted with EtOAc, washed with water, brine, dried over Na2SO4, and concentrated to give the inverted acetate 2 (2.2 g, 85 %).

References

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