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1-Allylisatin
(CAS RN:830-74-0 Product Number:A2943)

Structure

1-Allylisatin
Synonym 1-Allylindole-2,3-dione
Synonym 1-Allyl-2,3-indolinedione

General Information

Product Number A2943

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Purity/Analysis Method >98.0%(GC)
Storage Temperature
M.F. / M.W. C11H9NO2=187.20
CAS RN 830-74-0
Related CAS RN
MDL Number MFCD00224218
Packaging and Container
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Specification

Purity(GC) min. 98.0 %
Melting point 84.0 to 88.0 deg-C

Data of Reference

bp 145°C/1mmHg(lit.)
λmax 267(lit.)

References

Reaxys-RN 1528099
PubChem SID 354333758

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P264
  • :Wash hands and face thoroughly after handling.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Transport Information

HS Number 2933790090

Application

Multicomponent Reactions involving Arynes, Heterocycles, and Isatins

Experimental procedure: To a screw-capped test tube equipped is added 18-crown 6-ether (0.396 g, 1.5 mmol), KF (0.087 g, 1.5 mmol) and 1 (0.094 g, 0.50 mmol). Then the tube is evacuated and backfilled with argon. The mixture is dissolved in THF (2.0 mL). The resultant reaction mixture is kept stirring at 30 °C for 5 min. To the stirring solution is added pyridine (0.060 g, 0.75 mmol) and the 2-(trimethylsilyl)phenyl trifluoromethane sulfonate (0.223 g, 0.75 mmol) and the reaction mixture is stirred for 12 h at 30 °C. The reaction stops and the crude reaction mixture is purified by column chromatography (Pet. ether:EtOAc = 75 : 25) on silica gel to afford 2 (0.126 g, 73%) as a yellow solid.

References

PubMed Literature

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