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Silver Hexafluoroantimonate(V)
(CAS RN:26042-64-8 Product Number:S0463)

Structure

Silver Hexafluoroantimonate(V)

General Information

Product Number S0463

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Purity/Analysis Method >97.0%(T)
Storage Temperature
M.F. / M.W. AgSbF6=343.62
CAS RN 26042-64-8
Related CAS RN
MDL Number MFCD00003401
Packaging and Container
  • Product Details
  • Safety & Regulations

Specification

Purity(Precipitation Titration) min. 97.0 %

References

Reaxys-RN 11403824
PubChem SID 87575944
F&F 17,17
EC Number 247-429-1

GHS

Pictogram
Signal Word Danger
Hazard Statements
  • H302+H332
  • :Harmful by inhalation and if swallowed.
  • H314
  • :Causes severe skin burns and eye damage.
Precautionary Statements
  • P260
  • :Do not breathe dusts or mists.
  • P280
  • :Wear protective gloves, protective clothing, face protection.
  • P301+P330+P331+P310
  • :IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.
  • P303+P361+P353+P310+P363
  • :IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.
  • P304+P340+P310
  • :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor.
  • P305+P351+P338+P310
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Transport Information

UN Number 1759
Class 8
Packing Group III
HS Number 2843290000

Application

Ruthenium-catalyzed Direct C―H Amidation of Arenes

Typical Procedure:
Acetophenone (0.4 mmol), p-toluenesulfonyl azide (0.2 mmol), [RuCl2(p-cymene)]2 (4.9 mg, 4 mol%), AgNTf2 (12.5 mg, 16 mol%), NaOAc (3.3 mg, 20 mol%), and 1,2-dichloroethane (0.5 mL) are added to a screw-capped vial equipped with a spinvane triangular-shaped Teflon stirbar. The reaction mixture is stirred in a preheated oil bath at 80 °C for 12 h and then cooled to room temperature, filtered through a pad of Celite, and washed with ethyl acetate (10 mL×3). The filtrate is concentrated under reduced pressure and the residue is purified by chromatography on silica gel (n-hexane : EtOAc = 3 : 1) to give the desired product (56.1 mg, Y. 97%).

References

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