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Silver(I) Trifluoromethanethiolate
(CAS RN:811-68-7 Product Number:S0977)


Silver(I) Trifluoromethanethiolate
Synonym Trifluoromethanethiol Silver(I) Salt

General Information

Product Number S0977

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Purity/Analysis Method >95.0%(T)
Storage Temperature
M.F. / M.W. CAgF3S=208.93
CAS RN 811-68-7
Related CAS RN
MDL Number MFCD25563234
Packaging and Container
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Purity(Precipitation Titration) min. 95.0 %


Reaxys-RN 4151922
PubChem SID 354333285

Transport Information

HS Number 2843290000


Trifluoromethylthiolating Agent Usable for Direct Dehydroxytrifluoromethylthiolation of Alcohols


Experimental procedure3): AgSCF3 (251 mg, 1.2 mmol, 3.0 eq.) and TBAI (1330 mg, 3.6 mmol, 9.0 eq.) are combined in a Schlenk tube. The tube is mounted with a reflux condenser and backfilled with N2, then toluene (4.0 mL) and alcohol (0.4 mmol, 1.0 eq.) are added. The tube is placed into a preheated oil bath at 80 °C with vigorous stirring. After 10 h, the reaction mixture is cooled to room temperature and filtered through a plug of silica (eluted with EtOAc). The filtrate is concentrated, and the product is purified by column chromatography on silica gel to give the desired product.


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