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Silver Hexafluorophosphate
(CAS RN:26042-63-7 Product Number:S0981)

Structure

Silver Hexafluorophosphate

General Information

Product Number S0981

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Purity/Analysis Method >98.0%(T)
Storage Temperature
M.F. / M.W. AgPF6=252.83
CAS RN 26042-63-7
Related CAS RN
MDL Number MFCD00003415
Packaging and Container
  • Product Details
  • Safety & Regulations

Specification

Purity(Precipitation Titration) min. 98.0 %

Data of Reference

λmax 413(CHCl3)(lit.)

References

Reaxys-RN 13607729
PubChem SID 354333698
EC Number 247-428-6

GHS

Pictogram
Signal Word Danger
Hazard Statements
  • H290
  • :May be corrosive to metals.
  • H314
  • :Causes severe skin burns and eye damage.
Precautionary Statements
  • P260
  • :Do not breathe dusts or mists.
  • P280
  • :Wear protective gloves, protective clothing, face protection.
  • P301+P330+P331+P310
  • :IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.
  • P303+P361+P353+P310+P363
  • :IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.
  • P304+P340+P310
  • :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor.
  • P305+P351+P338+P310
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Transport Information

UN Number 3260
Class 8
Packing Group II
HS Number 2843290000

Application

A C-Arylation of N-Tosyl Aziridines

S0981

Experimental procedure: A mixture of 1 (1 mmol, 273 mg), anisole (2 mmol, 100 μL) and AgPF6 (0.02 mmol, 5 mg) in 3 mL of dry dichloroethane are stirred at 30 - 35 °C. Then the reaction mixture is diluted with water (5 mL) and extracted with dichloroethane (5 mL). The combined organic layers are dried over anhydrous sodium sulfate, concentrated in vacuo and the resulting product is purified by column chromatography on silica gel (ethyl acetate : petroleum ether = 1 : 10) to afford 2 (305 mg, 80% yield).

References

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