Home >   Products   >  Advanced Search

1-Naphthaleneboronic Acid (contains varying amounts of Anhydride)
(CAS RN:13922-41-3 Product Number:N0630)


1-Naphthaleneboronic Acid
Synonym 1-Naphthylboronic Acid (contains varying amounts of Anhydride)

General Information

Product Number N0630

* Items available from stock in Japan will be delivered in 10 business days.
* Please contact us if you need further information.
(Sales Dept Tel: +32 (0)3 735 07 00 E-mail: Sales-EU@TCIchemicals.com)
* To send your quote request for bulk quantities, please click on the “Request Bulk Quotation” button. Please note that for some of our products we cannot offer bulk quantities.
* TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.

Purity/Analysis Method
Storage Temperature
M.F. / M.W. C10H9BO2=171.99
CAS RN 13922-41-3
Related CAS RN
MDL Number MFCD00019722
Packaging and Container
  • Product Details
  • Safety & Regulations


Purity(Neutralization titration) 97.0 to 112.0 %


Beilstein 16(3)1280
Reaxys-RN 2937504
PubChem SID 87573946


Signal Word Warning
Hazard Statements
  • H302+H312+H332
  • :Harmful by inhalation, in contact with skin and if swallowed.
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P261
  • :Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P270
  • :Do not eat, drink or smoke when using this product.
  • P280
  • :Wear protective gloves, protective clothing, eye protection.
  • P302+P352+P312+P362+P364
  • :IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse.
  • P304+P340+P312
  • :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell.
  • P305+P351+P338+P337+P313
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Transport Information

HS Number 2931399090


Cyanation of Bronic Acids through Cross-Coupling Reaction

Typical Procedure:
Benzyl thiocyanate, the boronic acid (1.5 eq.), CuTC, and Pd(PPh3)4 (3 mol%) are added into a flask that is then flushed with argon. Dry and degassed 1,4-dioxane is added (2 mL for each 0.1 mmol benzyl thiocyanate). The brown suspension is stirred under argon at 100 ℃ for 12 h. Then Et2O (10 mL) is added and the reaction is washed with sat. NH4Cl followed by sat. Na2CO3 and then brine. After evaporation of the solvent, the residue is purified by preparative plate silica chromatography (hexane : AcOEt = 4 : 1) to give the desired nitrile compound.


Page Top