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Rhodium(II) Acetate Dimer
(CAS RN:15956-28-2 Product Number:R0069)

Structure

Rhodium(II) Acetate Dimer
Synonym Dirhodium(II) Tetraacetate
Synonym Tetrakis(acetato)dirhodium(II)

General Information

Product Number R0069

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Purity/Analysis Method
Storage Temperature
M.F. / M.W. C8H12O8Rh2=441.99
CAS RN 15956-28-2
Related CAS RN
MDL Number MFCD00003538
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Specification

Elemental analysis(Carbon) 20.50 to 22.70 %

References

Reaxys-RN 14201302
PubChem SID 87575627
F&F 15,278
RTECS# VI9361000
EC Number 240-084-8

Transport Information

HS Number 2843909000

Application

One-pot Synthesis of Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers

C2312,R0069

Typical Procedure:
Alkyne (0.2 mmol), TsN3 (1.0 eq.), alkenyl alkyl ether (3.0 eq.), CuTC (10.0 mol%), Rh2(OAc)4 (1.0 mol%), and DCE (0.2 M) are added to an oven-dried test tube under nitrogen atmosphere. The reaction mixture is stirred at ambient temperature for 3 h and then, heated at 80 °C for 4–13 h. After the reaction mixture is filtered through short path of celite with CH2Cl2, the filtrate is concentrated under reduced pressure. The residue is purified by silica gel column chromatography (ethyl acetate–hexane) to give pyrrole derivatives (Y. 65–81%).

References

Highly Diastereoselective Synthesis of Fully Substituted Tetrahydrofurans

Typical Procedure: A flask is charged with allyl alcohol (0.10 mmol, 1.0 eq.), Rh2(OAc)4 (2.0 mol%) and 4A MS (0.1 g) in toluene (1.5 mL), the reaction mixture is stirred at 45℃, and a solution of the diazo compound (0.20 mmol) in toluene (0.5 mL) is added to the reaction mixture over a period of 1 h through a syringe pump. After completion of the addition, piperidine (2.0 eq.) is added and the reaction mixture is stirred for additional 5-10 h (reaction completion is monitored by TLC) at 45℃. The reaction mixture is purified by flash chromatography on silica gel (EtOAc : light petroleum ether = 1 : 50 to 1 : 20) to give the pure product.

References

PubMed Literature

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